دانلود کتاب Efficient Preparations of Fluorine Compounds – آماده سازی کارآمد ترکیبات فلورین

توضیحات

The definitive guide to creating fluorine-based compounds?and the materials of tomorrow

Discovered as an element by the French chemist Henri Moissan in 1886, through electrolysis of potassium fluoride in anhydrous hydrogen fluoride?’le fluor,’ or fluorine, began its chemical history as a substance both elusive and dangerous. With a slight pale yellow hue, fluorine is at room temperature a poisonous diatomic gas. Resembling a spirit from a chemical netherworld, fluorine is highly reactive, difficult to handle, yet very versatile as a reagent?with the power to form compounds with almost any other element.

Comprising 20% of pharmaceutical products and 30% of agrochemical compounds, as well as playing a key role in electric cars, electronic devices, and space technology, compounds containing fluorine have grown in importance across the globe. Learning how to safely handle fluorine in the preparation of innovative new materials?with valuable new properties?is of critical importance to chemists today. Bringing together the research and methods of leading scientists in the fluorine field, Efficient Preparations of Fluorine Compounds is the definitive manual to creating, and understanding the reaction mechanisms integral to a wide variety of fluorine compounds. With sixty-eight contributed chapters, the book’s extensive coverage includes:

• Preparation of Elemental Fluorine
• Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications
• Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions
• Direct Fluorination of Organic Compounds with Elemental Fluorine
• Efficient Preparations of Bioorganic Fluorine Compounds
• Asymmetric Fluorocyclization Reactions
• Preparations of Rare Earth Fluorosulfides and Oxyfluorosulfides

The book offers methods and results that can be reproduced by students involved in advanced studies, as well as practicing chemists, pharmaceutical scientists, biologists, and environmental researchers. The only chemical resource of its kind, Efficient Preparations of Fluorine Compounds?from its first experiment to its last?is a unique window into the centuries old science of fluorine and the limitless universe of fluorine-based compounds.

Content:
Chapter 1 Preparation of Elemental Fluorine (pages 16): Karl O. Christe
Chapter 2 Preparation of Highly Active Cesium Fluoride (pages 78): Konrad Seppelt
Chapter 3 Preparation of Highly Active Silver Fluoride (pages 910): Konrad Seppelt
Chapter 4 A Room?Temperature Non?Irradiative Synthesis of XeF2 (pages 1115): Ulf Breddemann, John R. Debackere and Gary J. Schrobilgen
Chapter 5 Efficient Perfluorination of K2B12H12 in Neutral Acetonitrile (pages 1618): Dmitry V. Peryshkov, Eric V. Bukovsky and Steven H. Strauss
Chapter 6 Efficient Preparation of the Highly Soluble ortho? and para?C60(CF2C6F5)2 Derivatives (pages 1921): Igor V. Kuvychko, Bryon W. Larson, Steven H. Strauss and Olga V. Boltalina
Chapter 7 Synthesis of Cs[1?H?CB11F11] (pages 2225): Michal Valasek, Filip sembera, Michael J. Hughes, Ivan Stibor, Zbynek Janousek and Josef Michl
Chapter 8 Synthesis of Zero?Valent Trifluoromethyl Chalcogenato Derivatives, [NMe4]ECF3 (E = S, Se, Te), and Related Compounds (pages 2634): Wieland Tyrra and Silke Kremer
Chapter 9 Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications (pages 3559): Dayal T. Meshri, N. C. Mathur and Ritesh R. Jain
Chapter 10 Tris(pentafluorophenyl)borane, B(C6F5)3, a Powerful, Well?Soluble, Nonoxidizing Lewis Acid and the Weakly Coordinating Tetrakis(pentafluorophenyl)borate Anion, [B(C6F5)4]? (pages 6064): Hermann?Josef Frohn
Chapter 11 Pentafluorophenyldifluoroborane, C6F5BF2, and Pentafluorophenyltrifluorosilane, C6F5SiF3, Versatile Reagents for Fluorine/Pentafluorophenyl Substitution Reactions in Strongly Oxidizing Hypervalent Nonmetal Fluorides (pages 6571): Hermann?Josef Frohn
Chapter 12 Iodine(III and V) Fluorides: Interesting Fluorinating Agents (pages 7275): Hermann?Josef Frohn
Chapter 13 Tetramethylammonium Fluoride, [N(CH3)4]F, a Widely Applicable Reagent to Introduce Fluoride Ions and a Suitable Nucleophile to Initiate the Transfer of Perfluoroorganyl Groups to Electrophiles (pages 7678): Hermann?Josef Frohn
Chapter 14 Preparation of Transition Metal Sulfide Fluorides (pages 7981): Michael Gerken
Chapter 15 Transition Metal Carbonyl Sulfur Dioxide and Thiazylfluoride Complexes: Reactions at the Metal Center and at the Ligand (pages 8287): Rudiger Mews
Chapter 16 Cesium, Mercury, and Silver Salts with SulfurNitrogenFluorine Anions: Useful Transfer Reagents for NSF Building Blocks (pages 8893): Rudiger Mews
Chapter 17 Laboratory?Scale Synthesis of Gold Trifluoride and Uranium Hexafluoride (pages 9499): Thomas M. Klapotke
Chapter 18 Preparation of Transition Metal Fluorides using ClF3 (pages 100107): Ralf Haiges
Chapter 19 Preparation of Fluorine?Containing Molecular Halides and Heteropolar Salts with Elements of Group 15 and Niobium and Tantalum Halides (pages 108116): Lothar Kolditz
Chapter 20 Fluoro and Fluorohydroxy Complexes of As, Sb, and Sn (pages 117120): Lothar Kolditz
Chapter 21 Trifluoromethyl Compounds via Electrophilic and Nucleophilic Reactions (pages 121126): Jean’ne M. Shreeve
Chapter 22 Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions (pages 127132): Jean’ne M. Shreeve
Chapter 23 The Real Iodine and Bromine Monofluorides (pages 133138): Shlomo Rozen
Chapter 24 The Versatile Chemistry of Acetyl Hypofluorite: The First Hypofluorite Not Bonded to a Polyhaloalkyl Group (pages 139145): Shlomo Rozen
Chapter 25 Direct Fluorination of Organic Compounds with Elemental Fluorine (pages 146153): Shlomo Rozen
Chapter 26 The Surprising Chemistry of Bromine Trifluoride (pages 154172): Shlomo Rozen
Chapter 27 Preparation of Silicon? and Sulfur?Based Fluorinated Methane Derivatives as Versatile Fluoromethylation Reagents (pages 173204): G. K. Surya Prakash and Fang Wang
Chapter 28 Pentafluoroethyl Lithium: Reactions with Carbonyl Compounds and Epoxides (pages 205209): Olesya Kazakova and Gerd?Volker Roschenthaler
Chapter 29 Synthesis of ??Hydroxy??,??difluoromethylenephosphonates (pages 210213): Olesya Kazakova and Gerd?Volker Roschenthaler
Chapter 30 Synthesis of Pentafluoro??6?sulfanyl?Substituted Acetylenes for Liquid Crystals (pages 214219): Olesya Kazakova, Maxim Ponomarenko and Gerd?Volker Roschenthaler
Chapter 31 Delocalized Lipophilic Cations as a Source of Naked Fluoride and Phase?Transfer Catalysts (pages 220226): Nataliya Kalinovich, Olesya Kazakova and Gerd?Volker Roschenthaler
Chapter 32 Methyltrifluoropyruvate Imines Possessing N?oxalyl and N?Phosphonoformyl Groups: Precursors to a Variety of ??CF3???Amino Acid Derivatives (pages 227231): Olesya Kazakova and Gerd?Volker Roschenthaler
Chapter 33 Rhodium?Mediated Synthesis of (3,3,3?Trifluoropropyl)trimethoxysilane and (3,3,3?Trifluoropropyl)triphenylsilane (pages 232234): Falk Wehmeier and Thomas Braun
Chapter 34 Rhodium?Mediated Synthesis of a Tetrafluoropyridyl?2?boronate Ester (pages 235236): Michael Teltewskoi and Thomas Braun
Chapter 35 Palladium?Mediated Synthesis of 4?Vinyltetrafluoropyridine and 2,3,5,6?Tetrafluoropyridine (pages 237239): David Breyer and Thomas Braun
Chapter 36 Preparation of Polyfluoroaryl?1,2?difluorovinylsilanes (pages 240242): Donald J. Burton and Ba V. Nguyen
Chapter 37 Preparation of (Z)?2?iodo?1,2?Difluorostyrenes (pages 243245): Donald J. Burton and Ling Xue
Chapter 38 Preparation of 1,4?Bis(Z?2?iodo?1,2?difluoroethenyl)benzene (pages 246247): Donald J. Burton and Craig A. Wesolowski
Chapter 39 Stereospecific Carboamidation Route to (Z)?N?Phenyl?2,3?difluoro?3?(triethylsilyl) acrylamide (pages 248249): Donald J. Burton and Craig A. Wesolowski
Chapter 40 Preparation of 2?Trifluoromethyl?3,3,3?trifluoropropanal (pages 250251): Donald J. Burton and Donald A. Wiebe
Chapter 41 Synthesis of Tetrafluorocatechol (pages 252255): Sudharsanam Ramanathan, Dayong Sang, Vivek Kumar and David M. Lemal
Chapter 42 Preparation of an Unsymmetrical Bis((perfluoroalkyl)sulfonyl)imide (pages 256261): Darryl D. DesMarteau and Thomas D. Hickman
Chapter 43 Preparation of Perfluoroalkyl Sulfilimines and Sulfoximines (pages 262265): Emmanuel Magnier
Chapter 44 Preparation of Trifluoromethylsulfonium Salts (pages 266269): Emmanuel Magnier
Chapter 45 Preparation of Organometallic Fluorides of Main Group and Transition Elements (pages 270274): Herbert W. Roesky
Chapter 46 Preparation of Pentafluorosulfanyl Carbonyl Compounds (pages 275278): John T. Welch
Chapter 47 Preparation of Power?Variable Electrophilic Trifluoromethylating Agents, S?(Trifluoromethyl)dibenzothiophenium Salts Series (pages 279289): Teruo Umemoto
Chapter 48 Synthesis of Fluorine?Containing Heterocycles from ?,??Dihydropolyfluoroalkylsulfides and Fluorinated Thiocarboxylic Acids Derivatives (pages 290307): Vadim M. Timoshemko and Yuriy G. Shermolovich
Chapter 49 Synthesis of Octafluorocyclooctatetraene (pages 308314): John M. Buzby, Aldos C. Barefoot, Michael W. Grayston, Evan D. Laganis, Roy F. Waldron and David M. Lemal
Chapter 50 Preparation of Fluoroolefins (pages 315333): Moritz F. Kuehnel and Dieter Lentz
Chapter 51 Preparation of Ionic Liquids of Fluorocomplex and Oxofluorocomplex Anions by FluoroacidBase Reactions (pages 334337): Kazuhiko Matsumoto and Rika Hagiwara
Chapter 52 Synthesis of Difluorocyclopropyl Building Blocks: 2,2?Difluorocyclopropylmethanol and 2?(Bromomethyl)?1,1?difluorocyclopropane (pages 338342): Wei Xu and William R. Dolbier
Chapter 53 Preparation of 1,1,2,2,9,9,10,10?Octafluoro[2.2]paracyclophane and Perfluoro[2.2]paracyclophane (pages 343348): William R. Dolbier, Jian?Xi Duan, Alex J. Roche and Lianhao Zhang
Chapter 54 Synthesis and Application of gem?Difluoromethylenated and Trifluoromethylated Building Blocks (pages 349364): Feng?Ling Qing and Xiao?Long Qiu
Chapter 55 1,3?Dipolar Cycloaddition Reactions to Fluoroalkenes (pages 365369): Hanna Wojtowicz?Rajchel and Henryk Koroniak
Chapter 56 Synthesis of Fluorinated Vinyl Derivatives of Nucleic Acid Bases (pages 370374): Hanna Wojtowicz?Rajchel, Donata Pluskota?Karwatka and Henryk Koroniak
Chapter 57 Synthesis of CF3?Substituted Aziridine Ring by the Gabriel Reaction (pages 375378): Tomasz Cytlak, Bartosz Marciniak and Henryk Koroniak
Chapter 58 Preparation of ??Fluoro Amino and ??Fluoro Enamino Reagents (pages 379384): Justyna Walkowiak and Henryk Koroniak
Chapter 59 Synthesis of Original Fluoromonomers and Their Radical Copolymerization with Vinylidene Fluoride (pages 385395): Bruno Ameduri
Chapter 60 Convergent 18F Radiosynthesis (pages 396399): V. Gouverneur and O. Lozano
Chapter 61 Asymmetric Fluorocyclization Reactions (pages 400404): V. Gouverneur and O. Lozano
Chapter 62 Preparation of Allylic Fluorides (pages 405411): V. Gouverneur and O. Lozano
Chapter 63 Dehydroxyfluorinations of Primary or Secondary Alcohols Using Perfluoro n?Butylsulfonyl Fluoride (Nonaflyl Fluoride) in Combination with 1,8?Diaza?bicyclo[5.4.0]undec?7?ene (pages 412414): Orlin Petrov, Matthias Schneider, Rolf Bohlmann, Stephan Vettel and Helmut Vorbruggen
Chapter 64 Preparation of Rare Earth Fluorosulfides and Oxyfluorosulfides (pages 415424): A. Demourgues and A. Tressaud
Chapter 65 Preparation of CarbonFluorine Compounds and Fluoride or Oxide Fluoride?Intercalated Graphites (pages 425432): Tsuyoshi Nakajima
Chapter 66 Safe Synthesis of Superstoichiometric Mesoporous Fluorocarbons (pages 433441): Valentin N. Mitkin
Chapter 67 Preparation of Fluorinated ??Alumina (pages 442446): Erhard Kemnitz, Tomaz Skapin and John M. Winfield
Chapter 68 High?Yield Synthesis of a Single Asymmetric Isomer of C70(CF3)10 by High?Temperature Radical Trifluoromethylation (pages 447449): Natalia B. Shustova, Steven H. Strauss and Olga V. Boltalina

————————————————————–

ترجمه ماشینی :

راهنمای قطعی برای ایجاد ترکیبات مبتنی بر فلورین؟ و مواد فردا 1886 ، از طریق الکترولیز فلوراید پتاسیم در هیدروژن هیدروژن بی آب؟ ‘le fluor’ یا فلورین ، تاریخچه شیمیایی خود را به عنوان ماده ای گریزان و خطرناک آغاز کرد. فلورین با کمی رنگ زرد کم رنگ ، یک گاز دیاتومیک سمی در دمای اتاق قرار دارد. فلورین شبیه به روح از یک دنیای شیمیایی ، بسیار واکنشی است ، دشوار است که از آن استفاده کنید ، در عین حال بسیار متنوع به عنوان یک معرف؟ با قدرت تشکیل ترکیباتی با هر عنصر دیگر.